ABSTRACT Atrazine is an herbicide used to remove weeds in agricultural crops; however, because it is considered toxic, options for removing it from the environment are needed. Adsorption on biochar is an efficient technique for removing organic contaminants. In this study, the atrazine adsorption capacities of two biochars (BCA400 and BCA700) produced from rice husks at different pyrolysis temperatures (400 and 700 °C) were compared by phenomenological modeling. The biochars were characterized by SEM, FTIR and BET. Experimental kinetic and equilibrium data were obtained to evaluate Langmuir, Freundlich and BET isotherms and to conduct intraparticle diffusion. In comparison to BCA400, BCA700 showed a higher adsorption capacity at a higher pyrolysis temperature, and the Freundlich isotherm best described its system. To describe the kinetic adsorption data for the biochars, a phenomenological model based on intraparticle diffusion was applied, and the model fit well to these data for each biochar. This model is slow and involves the transport of atrazine to the pores of the biochar. Thus, the predictive model can be scaled up to adsorption systems.

ABSTRACT Atrazine is a herbicide widely used in agriculture; however, because of its toxicity, alternatives are needed to remove this compound from the environment. In this study, we investigated the adsorption process and the atrazine-adsorbing ability of three biochars produced at different pyrolysis temperatures from byproducts of the wood industry. The biochars were characterized by Fourier-transform infrared spectroscopy (FTIR) and scanning electron microscopy (SEM), and their physical characteristics were evaluated by Brunauer-Emmett-Teller (BET) analysis. The biochar pyrolyzed at 350 °C (BM350) adsorbed 26.04% of the herbicide, showing the best performance among the three biochars tested, even though it had the lowest specific surface area (1.467 m2 g–1). It also had a greater quantity of organic functional groups, which may have influenced the adsorption. The kinetics of the adsorption process were best explained by the pseudo-first-order model and by the Freundlich isotherm model. However, the biochar is not suitable for the removal of the herbicide atrazine, having a lower adsorption capacity than those of others described in the literature.

ABSTRACT: Soil application of swine wastewater for nutrient cycling may represent a correct destination of these residues and reduction in production costs. However, when applied to soil, such residue may cause environmental impacts. This study aimed to analyze the chemical characteristics of the soil, corn, and leachate after successive swine wastewater applications associated with mineral fertilization. The experiment was developed in drainage lysimeters under field conditions. Wastewater doses applied were 0, 100, 200, and 300 m3 ha−1 with and without mineral fertilization. The results were submitted to analysis of variance and Tukey's test. After nine years of application, a special attention should be taken regarding water quality from a dose of 200 m3 ha−1 since some elements may leach into the soil. In addition, a synchronism between residue application and crop requirements needs to be taken into account. Doses of 200 and 300 m3 ha−1 are considered as satisfactory to meet corn nutritional requirements. Moreover, an increase in fertility characteristics was observed, but a caution regarding Cu and Zn contents should be taken since these elements produce a cumulative effect in the soil.